Micrographs : Lead 80wt% Tin
Pb-80wt%Sn.
The first phase to precipitate from the liquid metal during slow cooling is tin (Sn) rich and it forms as dendrites. This occurs below approximately 200°C. The tin concentration in the liquid decreases as the temperature falls until it reaches the eutectic composition (38wt% Pb) at the eutectic temperature of 183°C. The remaining liquid solidifies as a eutectic.
The tin rich dendrites are the large dark phase. The fine dispersion of tin rich (97.5wt% Sn) and lead rich (81wt% Pb) can be seen in the eutectic matrix.
Tin has no solubility for lead below 150°C, and at high magnification fine lead precipitates can be seen within the tin dendrites.
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